The Effect of Precursor on the Optical Properties of Carbon Quantum ‎Dots Synthesized by Hydrothermal/Solvothermal Method
Paper ID : 1422-UFGNSM-FULL
Authors:
Afsaneh Mozdbar1, Amideddin Nouralishahi *2, Shohreh Fatemi1, Ghazaleh Mirakhori1
1University of Tehran
2Caspian Faculty of Engineering, Chouka town, Gilan, Iran
Abstract:
In the recent decade, Carbon Quantum Dots (CQDs) have attracted lots of attention due to their excellent properties such as tunable photoluminescence, high ‎chemical stability, low toxicity, and biocompatibility. Among all synthesis methods, the hydrothermal/solvothermal rout has been considered as one of the most ‎common and simplest method. The type of precursors can affect the size of CQDs and determine ‎their surface functional groups, the essential properties that deeply influence the optical ‎specifications. In this work, the effect of different precursors on the final properties ‎of carbon quantum dots is investigated. The carbon quantum dots were synthesized by hydrothermal/solvothermal ‎rout using citric acid, thiourea, ethylamine and monoethanolamine as precursors in almost the same ‎conditions of time and temperature. Resultant CQDs were characterized by using FTIR, UV-Visible Spectroscopy ‎and Photoluminescence (PL) analysis. The results of UV-Vis spectroscopy showed that quantum ‎dots synthesized from monoethanolamine have wider absorption band rather than the CQDs from other ‎precursors and the absorption edge shifted from about 270 nm for ethylamine to about 470 nm in ‎monoethanolamine. Furthermore, the results demonstrate that using citric acid and monoethanolamine as precursor ‎improved production efficiency and emission quantum yield of the carbon dots.
Keywords:
Carbon quantum dot (CQD), Photoluminescence (PL), Band gap, Citric acid, Thiourea, Ethylamine, ‎Mono ethanol amine
Status : Paper Accepted (Poster Presentation)