Removal of Cr(VI) from aqueous solution by modified ultrafiltration ‎membrane
Paper ID : 1233-UFGNSM-FULL
Authors:
maryam sadat kazemi *1, majid peyravi2, Mohsen Jahanshahi2
1Shariati Av., Babol, Mazandaran, Iran 47148 - 71167
2Nanotechnology Research Institute, School of Chemical Engineering, Babol University, ‎Babol, Iran
Abstract:
The drinking water containing hexavalent chromium [Cr(VI)], accumulating in the food ‎chain, is harmful to humans because of its carcinogenicity. In this study, a new adsorbent ‎thin film composite (TFC) membrane was prepared. Fabricated membrane was used for ‎removal of hexavalent chromium, from aqueous solution. Membranes were fabricated by ‎modification of ultrafiltration (UF) poly sulfone (PSF) membrane surface by layer of ‎chitosan as a cationic polyelectrolyte. Surface of PSF UF membranes are negatively charged ‎thus chitosan binds on its surface through electrostatic interactions. Modified membrane ‎characterized by atomic force microscopy (AFM) and contact angle analysis. According to ‎results of analysis, roughness of membrane surface decreases after modification of it by ‎chitosan and contact angle of modified membrane was decreased significantly. Reducing ‎the contact angle leads to increasing the hydrophilicity of modified membrane, this result ‎confirms by high water flux of modified membrane. For investigation performance of neat ‎and modified membrane in Cr(VI) removal were carried out the batch experiment and ‎filtration test. According to results, modified membrane has shown high efficiency for ‎removal of Cr(VI) from aqueous solution. Filtration test was performed in different initial ‎feed concentration. Results shows removal percent of Cr(VI) increases with reducing of ‎initial feed concentration.‎
Keywords:
Cr(VI) removal, Ultrafiltration, modification.
Status : Paper Accepted (Poster Presentation)