Electrical Properties and Enhance of photocatalytic activity ‎‎of TiO2 nanorods doped with aluminum oxide
Paper ID : 1070-UFGNSM-FULL
Authors:
Mehran Riazian *
Department of Engineering, Tonekabon branch, Islamic Azad University, Tonekabon, ‎Iran
Abstract:
In present work, Synthesis of TiO2 nanorods in anatase, rutile and Ti8O15 phases, ‎TiO2 nanorods ‎embedded with aluminum oxide as dopant by using the sol-gel ‎method and alkaline corrosion ‎are reported. The morphologies, crystal structures ‎and electrical properties of TiO2 ‎nanorods are characterized by use of field ‎emission scanning electron microscopy ‎‎(FE-SEM), atomic force microscopy ‎‎(AFM), tunneling electron microscopy ‎‎(TEM), X-ray diffractometer (XRD), UV-‎vis. Spectrophotometer and furrier ‎transmission create infrared absorption (FT-IR) ‎techniques. Degradation rate of methylen ‎blue (MB) in its aqueous solution under ‎UV irradiation is investigated as an ‎amount of photocatalytic activity. The ‎addition of aluminum oxide to the TiO2 matrix (as a dopant) enhances the ‎photocatalytic activity due to thermal stability and increasing in the surface area. ‎Dependence between photocatalytic activity ‎and calcination temperature is ‎determined. Dielectric constant, capacity, quality ‎factor and resistance is measured ‎by GPS 132 A technique. Moreover, the effects ‎of aluminum oxide dopant and ‎calcination temperatures on surface topography, crystallization ‎of phases, ‎dielectric constant, electrical resistance, lattice strain and activation ‎energy of ‎nanoparticles formation are studied. The obtained results show that Al2O3-doped ‎TiO2 nanorods have higher dielectric constant, higher photocatalytic activity, less ‎leakage current, less roughness surface, less lattice strain and higher thermal ‎stability. Thus this nanorods have the potential to be a good candidate as a gate ‎dielectric material for the future of FETs. ‎
Keywords:
Photocatalytic activity, Dielectric,Structure, Nanorods, TiO2, aluminum oxide dopant, Sol-Gel
Status : Paper Accepted (Poster Presentation)